Spider-Man 1967, Episode 20

”Sting of the Scorpion”: The Scorpion escapes prison to get back at Jonah Jameson and Spider-Man. The Scorpion breaks into Dr. Stillwell’s lab and drinks a toxic potion that mutates him into a twenty-foot-tall giant. He captures Jameson and starts rampaging into the city. Now, Spider-Man must find a way to return the Scorpion to his normal size in order to save Jameson. ”Trick or Treachery”: The Fly Twins break into a vault and frame Spider-Man for the crime in the process. The villains implant a “fly tracer” on Spider-Man in order to monitor his whereabouts and continue to frame him while committing crimes in the city. After discovering that he has been tricked, Spider-Man sets out to clear his name and corners the Fly Twins at a fur storage warehouse for a final battle.

From Marvel.com

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